Design, Sensing and Binding Abilities of Porphyrin-based Heterotopic Receptors with Well-defined Geometries

Authors

  • Galina Mamardashvili A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya st. 1, 153045 Ivanovo, Russia.
  • Nugzar Mamardashvili G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya st. 1, 153045 Ivanovo, Russia.
  • Oscar Koifman G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya st. 1, 153045 Ivanovo, Russia.

DOI:

https://doi.org/10.9734/bpi/ctcb/v3/2292A

Keywords:

Porphyrin, receptor, molecular recognition, host–guest interactions, binding cavities

Abstract

Recent advances in design, sensing and binding abilities of porphyrin-based heterotopic receptors with well-defined geometries towards anions, ion pairs and neutral molecules of various natures are analyzed, summarized and classified. Synthetic approaches to the tetrapyrrolic macrocycles and methods of their functionalization are presented. General principles, mechanisms and driving forces of the formation of porphyrin-based supramolecular complexes are discussed. Most attention is on the development of effective systems for controlled recognition, selective delivery, and prolonged release of substrates of different natures to their sites of functioning.

Published

2022-06-30

How to Cite

Galina Mamardashvili, Nugzar Mamardashvili, & Oscar Koifman. (2022). Design, Sensing and Binding Abilities of Porphyrin-based Heterotopic Receptors with Well-defined Geometries. Current Topics on Chemistry and Biochemistry Vol. 3, 1–56. https://doi.org/10.9734/bpi/ctcb/v3/2292A

Issue

Current Topics on Chemistry and Biochemistry Vol. 3

Section

Chapters