Synthesis and Applications of Xanthate Esters

Authors

  • Toreshettahally R Swaroop Department of Studies in Organic Chemistry, University of Mysore, Manasagangotri, Mysuru – 570 006, Karnataka, India.
  • Rajaghatta N Suresh Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru – 570 006, Karnataka, India.
  • Muddegowda Umashankara Department of Chemistry, Karnataka State Open University, Muktagangotri, Mysuru - 570 006, Karnataka, India.
  • Kanchugarakoppal S Rangappa Institution of Excellence, University of Mysore, Manasagangotri, Mysuru - 570 006, Karnataka, India.

DOI:

https://doi.org/10.9734/bpi/cbrp/v1/3943

Keywords:

Xanthate esters, synthesis, tosylmethyl isocyanide, carbamothioates, ethyl isocyanoacetate

Abstract

We herein present a base-induced cycloaddition of active methylene isocyanides like tosyl methyl isocyanide and ethyl isocyanoacetate with xanthate esters for the synthesis of 5-(alkoxy)-4-(tosyl/ethoxycarbonyl)-1,3-thiazoles in DMF. In addition, we have explored xanthate esters as alkylating agents for amines in the presence of an acid catalyst. Finally, the reaction between xanthate esters and aryl methyl isocyanides produced carbamothioates in the presence of a base in DMF.

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Published

2025-01-24

How to Cite

Toreshettahally R Swaroop, Rajaghatta N Suresh, Muddegowda Umashankara, & Kanchugarakoppal S Rangappa. (2025). Synthesis and Applications of Xanthate Esters. Chemistry and Biochemistry: Research Progress Vol. 1, 111–122. https://doi.org/10.9734/bpi/cbrp/v1/3943

Issue

Chemistry and Biochemistry: Research Progress Vol. 1

Section

Chapters