Synthesis, Characterization and Crystal Structure of Mononuclear Bis(2-aminopyridine) Zinc Complex
DOI:
https://doi.org/10.9734/bpi/rdcbr/v7/2729Keywords:
Synthesis, crystal structure, Bis(2-amino-pyridine)zinc complex, \(Zn(OAc)_2 ·2H_2O\)Abstract
In this paper, a simple one-pot synthesis, characterization and crystal structure of novel N-Zn complex is described. 1H and 13C NMR spectra were obtained using a Bruker AM-300 spectrometer. Infrared spectra were recorded on a Mattson Galaxy Series FTIR 3000 spectrometer. 2-Aminopyridine reacts with Zn(OAc)2·2H2O in alcohol and forms the mononuclear bis(2-aminopyridine)- zinc complex, whose structure was determined via X-ray diffraction analysis. The complex is also characterized by nuclear magnetic resonance (NMR) spectroscopy, infrared (IR) spectroscopy, mass spectrometry (MS), and elemental analysis. The crystal is a prism and has a spacegroup of P2(1)/n, with the following parameters: with a = 9.1914(8) Å, b = 13.8595(12) Å, c =13.2921(12) Å, \(\alpha\) = 90.00 º, \(\beta\) = 92.474 º, \(\gamma\) = 90.00 º, \(\lambda\) =0.7103°, V = 1691.7(3), Z = 4, Dc = 1.459 g/cm3, Mr = 371.69 and F (000) = 768, R = 0.0416, wR = 0.0793 for 3689.
