Investigation of Solution Behaviour of Potassium Halides in Aqueous Solution of L- Proline at Different Temperatures: A Physicochemical Approach

Authors

  • Partha Sarathi Sikdar Department of Chemistry, University of North Bengal, Darjeeling 734013, India.
  • Pritam De Department of Chemistry, University of North Bengal, Darjeeling 734013, India.
  • Firoj Alam Department of Chemistry, University of North Bengal, Darjeeling 734013, India.
  • Biswajit Ghosh Department of Chemistry, University of North Bengal, Darjeeling 734013, India.
  • Salim Ali Department of Chemistry, University of North Bengal, Darjeeling 734013, India.
  • Ayesha Hossain Department of Chemistry, University of North Bengal, Darjeeling 734013, India.
  • Antara Sharma Department of Chemistry, University of North Bengal, Darjeeling 734013, India.
  • Pranish Bomzan Department of Chemistry, University of North Bengal, Darjeeling 734013, India.
  • Kangkan Mallick Department of Chemistry, University of North Bengal, Darjeeling 734013, India.
  • Mahendra Nath Roy Department of Chemistry, University of North Bengal, Darjeeling 734013, India.

DOI:

https://doi.org/10.9734/bpi/pcsr/v5/3517B

Keywords:

Potassium chloride, potassium bromide, potassium iodide, l-proline, ion-solvent interaction

Abstract

An analysis on the molecular interactions of potassium halides in aqueous mixture of L-Proline have been studied by measuring density (\(\rho\)) and viscosity (\(\eta\)) at three different temperatures (298.15, 308.15 and 318.15 K). Apparent molar volume (\(\phi\)v ) and viscosity B-coefficients were derived using Masson equation  and  Jones-Dole equation respectively and these derived parameters interprets the existing ion-solvent and ion-ion interactions in solution. The structure-making or breaking capacity of the electrolyte under investigation has been discussed in terms of sign of (\(\varphi\)V0 /\(\delta\)T)p.

Published

2022-10-21

How to Cite

Partha Sarathi Sikdar, Pritam De, Firoj Alam, Biswajit Ghosh, Salim Ali, Ayesha Hossain, … Mahendra Nath Roy. (2022). Investigation of Solution Behaviour of Potassium Halides in Aqueous Solution of L- Proline at Different Temperatures: A Physicochemical Approach. Progress in Chemical Science Research Vol. 5, 57–73. https://doi.org/10.9734/bpi/pcsr/v5/3517B

Issue

Progress in Chemical Science Research Vol. 5

Section

Chapters