Progress in Chemical Science Research Vol. 5

Abstract

An analysis on the molecular interactions of potassium halides in aqueous mixture of L-Proline have been studied by measuring density ($\rho$) and viscosity ($\eta$) at three different temperatures (298.15, 308.15 and 318.15 K). Apparent molar volume ($\varphi$v ) and viscosity B-coefficients were derived using Masson equation  and  Jones-Dole equation respectively and these derived parameters interprets the existing ion-solvent and ion-ion interactions in solution. The structure-making or breaking capacity of the electrolyte under investigation has been discussed in terms of sign of ($\phi$_V⁰ /$\delta$T)_p.