A Physicochemical Study to Evaluate the Subsistence of Inclusion Complexes of Cyclodextrins with 1-Butyl-2, 3-dimethylimidazolium Tetrafluoroborate Probe

Authors

  • Kalipada Sarkar Department of Chemistry, Islampur College, Islampur, Uttar Dinajpur: 733202, India.
  • Debadrita Roy Department of Chemistry, University of North Bengal, Darjeeling: 734013, India.
  • Sanjoy Barman Department of Chemistry, University of North Bengal, Darjeeling: 734013, India.
  • Baishali Saha Department of Chemistry, University of North Bengal, Darjeeling: 734013, India.
  • Siti Barman Department of Chemistry, University of North Bengal, Darjeeling: 734013, India.
  • Mahendra Nath Roy Department of Chemistry, University of North Bengal, Darjeeling: 734013, India and  Alipurduar University, Alipurduar-736122, India.

DOI:

https://doi.org/10.9734/bpi/ctcb/v2/2160B

Keywords:

Host- guest inclusion complex, ionic liquid, cyclodextrin, surface tension, Conductance

Abstract

Ionic liquids (ILs) are nonvolatile, nonflammable and thermally stable solvents. They are termed green solvents since they do not harm the environment. In aqueous medium, Inclusion complexes of ionic liquid, 1-butyl-2,3-dimethylimidazolium tetrafluoroborate (BDMImBF4) into cavity of hollow cylinder oligosaccharide, \(\boldsymbol{\alpha}\)- and \(\boldsymbol{\beta}\)-cyclodextrins are manifested. Surface tension and conductance experiments verify the stoichiometry of interfacial inclusion, while IR and 1HNMR spectroscopy confirm the inclusion phenomena. Volumetric and viscometric tests are used to analyze the interaction between cyclodextrin and ionic liquid.

Published

2022-06-08

How to Cite

Kalipada Sarkar, Debadrita Roy, Sanjoy Barman, Baishali Saha, Siti Barman, & Mahendra Nath Roy. (2022). A Physicochemical Study to Evaluate the Subsistence of Inclusion Complexes of Cyclodextrins with 1-Butyl-2, 3-dimethylimidazolium Tetrafluoroborate Probe . Current Topics on Chemistry and Biochemistry Vol. 2, 91–105. https://doi.org/10.9734/bpi/ctcb/v2/2160B

Issue

Current Topics on Chemistry and Biochemistry Vol. 2

Section

Chapters