Rhodium-phosphite Catalysed Hydroformylation of Camphene and Other Terpenes

Authors

  • Nitin S. Pagar Homogeneous Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India and Post Graduate Department of Chemistry, Sir Parshurambhau College, (Affiliated to Savitribai Phule Pune University), Pune-411030, India.
  • Raj M. Deshpande Homogeneous Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India.

DOI:

https://doi.org/10.9734/bpi/cpcs/v7/6608D

Keywords:

Hydroformylation, rhodium, phosphite, camphene, terpenes, kinetic

Abstract

The hydroformylation of camphene and other terpenes has been studied with homogeneous Rh, Co, and Pt metal complexes. Rh(CO)2(acac)/P(OPh)3 catalyst system has been found to be very active with almost total selectivity to aldehyde products. The role of ligands, solvents, Rh:P ratio and reaction conditions on the activity and selectivity towards camphene hydroformylation have been assessed. Kinetics of hydroformylation of camphene was investigated in the presence of [Rh(CO)2(acac)]/ P(OPh)3 catalyst in a temperature range of 363–383K.

Published

2021-02-06

How to Cite

Nitin S. Pagar, & Raj M. Deshpande. (2021). Rhodium-phosphite Catalysed Hydroformylation of Camphene and Other Terpenes. Current Perspectives on Chemical Sciences Vol. 7, 30–38. https://doi.org/10.9734/bpi/cpcs/v7/6608D

Issue

Current Perspectives on Chemical Sciences Vol. 7

Section

Chapters