Synthesis and Characterization of Cu(I) and Cu(II) Complexes Formed Through Carbon Disulfide Insertion

Authors

  • Samim Sultana Department of Chemistry, Dibrugarh University, Dibrugarh-786004, Assam, India.
  • Pradip. K. Gogoi Department of Chemistry, Dibrugarh University, Dibrugarh-786004, Assam, India.

DOI:

https://doi.org/10.9734/bpi/cacb/v6/8230D

Keywords:

Carbon disulphide, Insertion, copper complexes, ligand, coordination compound

Abstract

Two copper complexes [(PPh3)2Cu(S2COC2H5)] (A) and [(C3H4N2)2Cu(S2COC2H5)] (B) have been synthesized by the insertion of CS2  in (PPh3)2CuCl2 and (C3H4N2)2CuCl2, respectively in mixed solvent of dichloromethane and ethanol at room temperature. The complexes have been characterized by FTIR and ESR spectroscopy. Both the complexes have been found to be air-stable and are distorted square planar geometry.

Published

2021-05-28

How to Cite

Samim Sultana, & Pradip. K. Gogoi. (2021). Synthesis and Characterization of Cu(I) and Cu(II) Complexes Formed Through Carbon Disulfide Insertion. Current Advances in Chemistry and Biochemistry Vol. 6, 146–151. https://doi.org/10.9734/bpi/cacb/v6/8230D